Zinc oxide

Zinc oxide (ZnO) is formed by oxidation of zinc or zinc vapor but may also be obtained through calcination of zinc hydroxide. In contrast to most other substances, zinc oxide sublimates at normal pressure and at temperature increases passing directly from the solid into the gaseous state of aggregation instead of forming a (liquid) melt. Currently, hundreds of tons of micro-scale or pigmentary zinc oxide are consumed worldwide as e.g., additives that promote vulcanization in the production of rubber for automobile tires and that due to their good thermal conductivity support removal of the heat that is caused by churning. Zinc oxide improves the water resistance and prolongs the workability time of cement. It is used, moreover, in pharmaceutical ointments and pastes, plasters and bandages. “Zinc white” is found in wall paints and paint-boxes.

Nanostructured zinc oxide particles are transparent in the visible range of the spectrum and act as physical filters against the UVB and especially UVA radiation of the sun. Since the particles act as small mirrors that absorb and reflect the UV rays, they have become interesting sun protective additives. In spite of their tiny size, these particles are not absorbed from sun protection products by healthy skin. This has been shown by investigations conducted by industrial firms as well as by independent studies carried out within the framework of the EU project NANODERM. Since zinc oxide is characterized both by its UVA/UVB protection properties and by transparency, it is used in textiles as well as in clear varnishes applied in the wood and furniture industry. The ZnO nanoparticles that are used in artificial glass are highly transparent (> 90 % light transmission) in the visible spectral area and opaque to UV radiation (< 10 % light transmission) for wave lengths below 360 nm. Zinc oxide is used to provide semiconductors with transparent conductive layers and is found, in addition, in blue light emitting diodes (LED), liquid-crystal display devices with thin-film transistors (TFT), varistors (VDR - voltage-dependent resistors), and thin-layer solar cells.

Selbstorganisation von Zinkoxid: ZnO-Nanosäulen

 



Literature

  1. Römpp online
  2. Klingshirn et al. (2006) Physik Journal, 5 (1)
  3. Klingshirn (2007) ChemPhysChem, 8, 782 ? 803
  4. Fallert et al. (2008) Optics Express 16 (2)
  5. http://www.nanoproducts.de/
  6. http://www.uni-leipzig.de/~nanoderm/
  7. http://corporate.basf.com/de/

 

NanoCare data sheet for download

Data sheet zinc oxide.pdf

updated on 13.11.2009

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